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Then you tell Bob about how he would be much better suited for job A or B, explain how the pay is less, and if he's cool with it, directly put his CV into the pile for that job. If he's not cool with it, shake his hand and wish him a good day
What if there was no job posting with a defined salary for A or B?

Sounds like lose-lose.

If you're not hiring for that job, why are you telling Bob that he'd be really well suited there?