You are correct that the first law of thermodynamics dictates the energy, but anyone who has parked a car in the sun will tell you, the temperature where the absorption/dissipation equilibrium is achieved is often incompatible with the survival of the cargo.
edit to your edit:
> Edit: ISS is about 90KW steady state, and the collector to radiator area ratio is about 5:1. Dunno about the mass ratio.
Cool; that's about half the wattage of one modern full-height Nvidia AI rack (172kW) - you need two ISSes to service just 1 rack; extrapolate that to a data center's worth of racks and see if the math is mathing. The ISS is about the size of a(n American) football field.
You won't immediately freeze if you enter space without a suit. You'll die almost immediately, but it will be because your blood will begin to boil because of the lack of pressure kinda like an extreme form of divers sickness - it's just not the cold that'll get you first.