Multipath TCP is a neat trick that allows a single TCP connection (TCP = Transport Control Protocol, a stateless protocol for long running connections) to use multiple physical interfaces. You could do something similar before MTCP using bonding, but this was annoying to set up and usually required application level code to efficiently use the bonded connection. MTCP makes this much simpler from an application level point of view and it can use widely diverse underlying transport layers at the same time (for instance, WiFi, Cellular and wired connections).
It's an extension to TCP that, similar to QUIC, allows you to use multiple address/port pairs to transmit data over a single logical stream. Both client/initiator and server/listener have to opt into the extension. This might need to be enabled explicitly by the application[1], which Go apparently does for you, or judging from other posts may be enabled by default systemwide, depending on your platform.
AFAIU, a major user of MPTCP is Apple and the iPhone, and the ubiquity of iPhone clients motivated implementation in and deployment on Linux servers.
[1] https://docs.kernel.org/networking/mptcp.html#sockets-api