I also have a shared account in Germany, but paying with that doesn't work either. It shows an info page about what Wero is supposed to be, not a payment page. The page says I need to make a Google account and buy a compatible phone to download their software and try again
This is advertised as a replacement for iDeal, a Dutch system created by a collaboration of banks in 2005. It worked very simple on any device: (1) click pay, (2) select your bank, (3) you're redirected to your bank's website and use your normal online banking method to authenticate the transaction (chip+pin with an authenticator, the mobile app, whatever your bank offers), (4) the website redirects you back to the merchant
Wero seems to be like a payment request, except it hides the target IBAN and requires an app and only allows certain banks from a few countries (not EU-wide). What a leap forward from iDeal that just always worked in any browser and bank when the payment provider supports it