Carbon does not beat metal structurally. Some organic polymers are competitive in tensile strength. In flexural strength and fracture toughness, alloys continue to rule. And when carbon materials are competitive in strength and toughness, they tend to be highly temperature-sensitive and have sudden failure modes, which is not great for operating in space. Consider e.g. the Titan submarine that failed due to carbon fiber composite fatigue.
All our structural carbon is low tech by the relevant standards (civilization that can send star-seeds). https://dspace.mit.edu/entities/publication/49f95196-2ddf-48...