The weird structure of the electrons in the silicon cycle may be useful as a catalyst(or not, it's too early to be sure). Imagine it is like the Platinum in the car exhaust, not the solvent in the paint remover.
On the other hand, silicone resins and elastomers are already in widespread use in applications where resistance to high temperatures or burning is required (silicone =/= silicon, the former coming from silic-on + ket-one, a name based on a wrong hypothesis).
However, their mechanical resistance is usually modest, so if that is important they must be used either in combinations with other materials or reinforced, e.g. with glass fiber.
They are also more expensive than hydrocarbon-based plastics, so they are typically used only where strictly necessary.